A Stable Saddle-Shaped Polycyclic Hydrocarbon with an Open-Shell Singlet Ground State
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چکیده
منابع مشابه
A Stable Saddle-Shaped Polycyclic Hydrocarbon with an Open-Shell Singlet Ground State.
Diindeno-fused bischrysene, a new diindeno-based polycyclic hydrocarbon (PH), was synthesized and characterized. It was elucidated in detailed experimental and theoretical studies that this cyclopenta-fused PH possesses an open-shell singlet biradical structure in the ground state and exhibits high stability under ambient conditions (t1/2 =39 days). The crystal structure unambiguously shows a n...
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Magnetic properties are studied of a system having two types of electronic singlet-ground-state ions, d-ion (singlet-doublet) and t-ion (singlet-triplet), by taking account of the hyperfine coupling. It is shown that the exchange interaction between the d-ion and the t-ion electronic spins affects crucially the magnetic properties. The results are discussed in connection with the experimental r...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2017
ISSN: 1433-7851
DOI: 10.1002/anie.201611689